Chemical elements
  Nickel
    History
    Occurrence
    Isotopes
    Energy
    Production
    Preparation
    Application
    Catalyst
    Physical Properties
    Compounds
      Nickel Fluoride
      Nickel Dichloride
      Double Nickel Chlorides
      Nickel Dibromide
      Nickel Di-iodide
      Nickel Chlorate
      Nickel Perchlorate
      Nickel Bromate
      Nickel Iodate
      Tri-nickel Suboxide
      Nickel Suboxide
      Nickel Monoxide
      Nickel Dihydroxide
      Nickelo-nickelic Oxide
      Nickel Dioxide
      Nickel Subsulphide
      Nickel Monosulphide
      Nickel Sesquisulphide
      Tri-nickel Tetrasulphide
      Nickel Disulphide
      Nickel Tetrasulphide
      Nickel Sulphite
      Nickel Thiosulphate
      Nickel Dithionate
      Nickel Sulphate
      Nickel Subselenide
      Nickel Selenide
      Nickel Sesquiselenide
      Nickel Selenite
      Nickel Sesquitelluride
      Nickel Tellurite
      Nickel Chromate
      Nickel Dichromate
      Double Nickel Chromates
      Nickel Molybdate
      Nickel Nitride
      Nickel Azoimide
      Nickelamide
      Nitro-nickel
      Nickel Nitrite
      Nickel Nitrate
      Di-nickel Phosphide
      Nickel Sesquiphosphide
      Nickel Diphosphide
      Nickel Triphosphide
      Nickel Hypophosphite
      Nickel Phosphite
      Nickel Metaphosphate
      Nickel Orthophosphate
      Nickel Pyrophosphate
      Nickel Thio-orthophosphate
      Nickel Thiopyrophosphite
      Nickel Thiopyrophosphate
      Tri-nickel Diarsenide
      Nickel Arsenide
      Nickel Diarsenide
      Nickel Arsenite
      Nickel Orthoarsenate
      Nickel Antimonide
      Nickel Antimonate
      Nickel Thioantimonite
      Nickel Vanadate
      Nickel Carbide
      Nickel Tetracarbonyl
      Nickel Carbonate
      Nickel Monocyanide
      Nickel Cyanide
      Nickel Thiocyanate
      Nickel Thiocarbonate Hexammoniate
      Nickel Subsilicide
      Nickel Orthosilicate
      Nickel Monoboride
      Nickel Borates
    PDB 1a5n-1g2a
    PDB 1g3v-1mn0
    PDB 1mro-1s9b
    PDB 1scr-1xmk
    PDB 1xu1-2cg5
    PDB 2cqz-2jih
    PDB 2jk8-2v4b
    PDB 2vbq-3c2q
    PDB 3c6c-3h85
    PDB 3hdp-3kvb
    PDB 3l1m-3o00
    PDB 3o01-4ubp
    PDB 8icl-9ant

Nickel Selenite, NiSeO3






Nickel Selenite, NiSeO3, has been prepared in several stages of hydration. The semihydrate, 2NiSeO3.H2O, is obtained as insoluble rhombic prisms by heating a solution of nickel carbonate in selenious acid to 230° C. in sealed tubes. It is stable at 100° C. The monohydrate, NiSeO3.H2O, is precipitated on addition of an alkali selenite to a solution of a nickel salt. On drying over sulphuric acid it becomes a grey powder. The dihydrate, NiSeO3.2H2O, has also been obtained. Nickel Selenate, NiSeO4.6H2O, may be obtained as green octahedral crystals by allowing a solution of nickel carbonate in selenic acid to evaporate slowly at ordinary temperature.

Nickel selenate unites with the selenates of the alkali metals to yield double salts of the type M2SeO4.NiSeO4.6H2O. These salts crystallise in holohedral prisms belonging to the monoclinic system, and are isomorphous with the double sulphates of analogous composition, of which ferrous ammonium sulphate is the best known example. The following salts have been carefully studied by Tutton: potassium nickel selenate, K2SeO4.NiSeO4.6H2O (density at 20° C. 2.559, molecular volume 206.14); and the nickel selenates of rubidium (density 2.856, molecular volume 219.96), caesium (density 3.114, molecular volume 229.17) and ammonium (density 2.243, molecular volume 216.53).


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