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Nitro-nickel, Ni2NO2

When nitrogen peroxide, suitably diluted with nitrogen, is passed over reduced nickel, a black mass of Nitro-nickel, Ni2NO2 is obtained. Water decomposes it vigorously. When heated in a current of nitrogen nitrous fumes are first evolved, then the substance decomposes with violence, leaving a residue of nickel and its oxide.
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